Low-Cost Electrodeposition of Size-Tunable Single-Crystal ZnO Nanorods

Autor: Elias Sakellis, Antonis Markopoulos, Christos Tzouvelekis, Manolis Chatzigeorgiou, Anastasios Travlos, Nikos Boukos
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Fibers, Vol 9, Iss 6, p 38 (2021)
Druh dokumentu: article
ISSN: 2079-6439
DOI: 10.3390/fib9060038
Popis: In this paper we report a low cost, simple, electrochemical method for large-area growth of single crystal ZnO nanorods. The method utilizes a metallic zinc foil as the source of the necessary zinc ions for ZnO growth on indium-doped tin oxide (ITO) glass slides. The method is thoroughly discussed and investigated varying all the parameters involved. The resulting ZnO nanorods are highly oriented along c-axis and densely packed, while their length and diameter can be tuned by varying the growth parameters. Two different types of seed layers on the ITO glass slides are tested. A seed layer made by spin coating of ZnO nanoparticles results in a twofold increase of the ZnO nanorod surface density as compared with a ZnO thin film seed layer by physical vapor deposition. Additionally, the effect of oxygen supply during electrodeposition was investigated as a crucial regulatory parameter not only for the geometrical and topological characteristics of the ZnO nano-arrays but for their physical properties as well.
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