The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes
| Autor: | Matthew Gregson, Erli Lu, David P. Mills, Floriana Tuna, Eric J. L. McInnes, Christoph Hennig, Andreas C. Scheinost, Jonathan McMaster, William Lewis, Alexander J. Blake, Andrew Kerridge, Stephen T. Liddle |
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| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: | |
| Zdroj: | Nature Communications, Vol 8, Iss 1, Pp 1-11 (2017) |
| Druh dokumentu: | article |
| ISSN: | 2041-1723 35270993 |
| DOI: | 10.1038/ncomms14137 |
| Popis: | The inverse-trans-influence has been shown to operate in high oxidation state actinide complexes. Here, the authors report tetravalent cerium, uranium and thorium bis(carbene) complexes with trans C=M=C cores where experimental and theoretical data also suggest the presence of an inverse-trans-effect. |
| Databáze: | Directory of Open Access Journals |
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