Geochemical Characteristics of Catalytic Hydrogenation of Low-Mature Kerogen Under Deep Fluids

Autor: Xiaowei Huang, Zhijun Jin, Quanyou Liu, Qingqiang Meng, Dongya Zhu, Lu Wang, Jiayi Liu, Panpan Zhang, Jingbin Wang
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Frontiers in Earth Science, Vol 10 (2022)
Druh dokumentu: article
ISSN: 2296-6463
DOI: 10.3389/feart.2022.885860
Popis: There is increasingly valued attention on whether the matter and energy carried in the deep fluids can significantly change the hydrocarbon (HC) generation of low-mature source rocks. Previous studies suggest that the upward movement of deep fluids to sedimentary basins will change the HC generation evolution mode of low-mature source rocks, and the matter and energy carried by the fluid will transform the evolution process as transient events. However, there is a lack of quantitative evaluation of the specific changes of gaseous HC generation in the process of modification. In this study, the effect of deep fluids on HC generation and evolution of low maturity source rocks were quantitatively studied through simulation experiments of the gold tube closed system. We quantitatively selected hydrogen and catalysts (ZnCl2 and MoS2) to conduct catalytic hydrogenation of kerogen and explore the quantitative effects of deep fluids on HC generation in low-mature source rocks. Through the experimental results, it is found that catalytic hydrogenation has significant changes in a HC generation transformation of organic matter (OM). With the increase of catalytic hydrogenation reaction intensity, the maximum gaseous HC generation yield is 3.16–3.24 times that of the control groups without hydrogenation. In the relatively low-temperature stage (
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