Self-activated rare-earth free phosphor prepared by propylene glycol-modified silane

Autor: Hyun-Joo Woo, Teaho Kim
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Results in Chemistry, Vol 5, Iss , Pp 100824- (2023)
Druh dokumentu: article
ISSN: 2211-7156
DOI: 10.1016/j.rechem.2023.100824
Popis: A facile wet-chemistry method can be applied to produce efficient rare-earth-free LED phosphors. In this study, self-activated Ca2SiO4 phosphor was developed using a propylene glycol-modified silane (PGMS) as a silicate source. The structural and luminescence properties of samples were characterized using synchrotron X-ray powder diffraction and photoluminescence (PL) spectroscopy, respectively. The PGMS phosphor consists of mixed crystal phases of α′L, β, and γ, whereas the solid-state reaction (SSR) phosphor only has a β phase. The synthesized PGMS phosphor with distinctive crystal defects shows self-activated luminescence, while the SSR phosphor has no PL properties.
Databáze: Directory of Open Access Journals