Di-μ-chlorido-bis[aqua(2,2′-bipyridine-κ2N,N′)chloridocobalt(II)]
| Autor: | Li-Li Zhu, Yu Sun, Huai-Hong Zhang, Yun Wang, Bai-Wang Sun |
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| Jazyk: | angličtina |
| Rok vydání: | 2009 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 65, Iss 8, Pp m991-m991 (2009) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536809027846 |
| Popis: | The title complex, [Co2Cl4(C10H8N2)2(H2O)2], is composed of two CoII atoms, each hexacoordinated by three Cl atoms, one 2,2′-bipyridine (bpy) ligand and one water molecule in a distorted octahedral geometry. Neighboring CoII atoms are linked together by two Cl bridges, forming a dinuclear CoII complex with inversion symmetry. There are intermolecular O—H...Cl hydrogen bonds and intermolecular π–π stacking interactions between adjacent bpy ligands [centroid–centroid distance = 3.617 (2) Å] in the structure. |
| Databáze: | Directory of Open Access Journals |
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