Acetonitriletrichloridobis(cyclohexyldiphenylphosphane)rhodium(III) acetonitrile disolvate
| Autor: | Theunis J. Muller, Hendrik G. Visser, Andreas Roodt |
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| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 67, Iss 12, Pp m1785-m1786 (2011) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536811047477 |
| Popis: | In the title compound, [RhCl3(CH3CN)(C18H21P)2]·2CH3CN, the complex molecule lies on a twofold rotation axis that passes through the RhIII atom, one Cl atom, and the C and N atoms of the coordinated acetonitrile molecule. The RhIII atom is coordinated by two P atoms in trans positions, three Cl atoms and an acetonitrile molecule in a distorted octahedral geometry. Intramolecular C—H...Cl interactions are observed. The uncoordinated acetonitrile molecule is disordered over two sites with occupancies of 0.588 (4) and 0.412 (4). |
| Databáze: | Directory of Open Access Journals |
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