[(1R,4S)-(+)-3-Benzoyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-olato-κ2O2,O3](η4-norbornadiene)rhodium(I)

Autor: Mohamed Anoir Harrad, Brahim Boualy, Mustapha Ait Ali, Larbi El Firdoussi, Corrado Rizzoli
Jazyk: angličtina
Rok vydání: 2010
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 66, Iss 8, Pp m915-m916 (2010)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S160053681002667X
Popis: In the title complex molecule, [Rh(C17H19O2)(C7H8)], the rhodium(I) metal centre is coordinated by the O atoms of a benzoylcamphorate anion and the C=C bonds of the norbornadiene molecule into a slightly distorted square-planar coordination geometry. The six-membered chelate ring is essentially planar (r.m.s. deviation = 0.0378 Å) and forms a dihedral angle of 31.67 (11)° with the phenyl ring.
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