Bis{4-chloro-2-[(2-hydroxyethyl)iminomethyl]phenolato}nickel(II) monohydrate

Autor: Chen-Yi Wang, Jin-Yun Ye, Xiang Wu, Zhi-Ping Han
Jazyk: angličtina
Rok vydání: 2011
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 67, Iss 9, Pp m1229-m1229 (2011)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536811031680
Popis: The title mononuclear nickel(II) complex, [Ni(C9H9ClNO2)2]·H2O, was obtained by the reaction of 5-chlorosalicylaldehyde, 2-aminoethanol and nickel nitrate in methanol. The Ni atom is six-coordinated by two phenolate O, two imine N and two hydroxy O atoms from two crystallographically different Schiff base ligands, forming an octahedral geometry. In the crystal, molecules are linked through intermolecular O—H...O and O—H...Cl hydrogen bonds.
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