Chlorido[N′-(2-oxidobenzilidene)acetohydrazide-κ2O,N′,O′]copper(II) dihydrate

Autor: Youssouph Bah, Aliou Hamady Barry, Abdou Salam Sall, Mohamed Gaye, Farba Bouyagui Tamboura
Jazyk: angličtina
Rok vydání: 2009
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 65, Iss 2, Pp m160-m161 (2009)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536809000105
Popis: In the title complex, [Cu(C9H9N2O2)Cl]·2H2O, prepared from the Schiff base ligand N′-(2-hydroxybenzilidene)acetohydrazide and copper(II) chloride, the CuII atom is coordinated by two O atoms and one N atom from the ligand and by a Cl atom in a distorted square-planar geometry. The two donor O atoms of the tridentate Schiff base ligand are in a trans arrangement. In the crystal structure, there is an extensive intermolecular hydrogen-bonding network; N—H...O, O—H...O and O—H...Cl interactions, involving the uncoordinated water molecules, lead to the formation of a two-dimensional network parallel to the ab plane.
Databáze: Directory of Open Access Journals