(Ethylenediamine-κ2N,N′)bis(perchlorato-κO)bis(pyridine-κN)copper(II)
| Autor: | Ali Ourari, Nawel Bounab, Sofiane Bouacida, Djouhra Aggoun |
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| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 68, Iss 8, Pp m1030-m1031 (2012) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536812029868 |
| Popis: | In the title compound, [Cu(ClO4)2(C2H8N2)(C5H5N)2], the CuII cation is located on a twofold rotation axis and is coordinated by four N and two O atoms in a tetragonally distorted octahedral geometry. The crystal packing can be described as ClO4 tetrahedra and CuN4O2 octahedra alternating in a zigzag fashion along the c axis. The structure is stabilized by intermolecular N—H...O and C—H...O hydrogen bonds, as well as π–π interactions [centroid–centroid distance = 3.7179 (15) Å]. |
| Databáze: | Directory of Open Access Journals |
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