Tetra-μ3-hydroxido-tetrakis[tricarbonylrhenium(I)] pyridine tetrasolvate
| Autor: | M. Schutte, A. Brink, H. G. Visser, A. Roodt |
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| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 68, Iss 9, Pp m1208-m1209 (2012) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536812036033 |
| Popis: | The title compound, [Re4(μ3-OH)4(CO)12]·4C5H5N, crystallizes with one tetranuclear rhenium(I) cubane-like molecule and four pyridine molecules in the asymmetric unit. The coordination environment of each ReI atom is distorted octahedral. Four intramolecular O—H...N and four intermolecular C—H...O hydrogen-bond interactions are observed. Relatively strong hydrogen bonds are found between the hydrogen-bond donor (μ3-OH) and acceptor (basic N atom of pyridine), with N...O distances between 2.586 (10) and 2.628 (10) Å. Intercube distances of 9.873 (2) and 12.376 (3) Å are observed. |
| Databáze: | Directory of Open Access Journals |
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