Two-Dimensional and Three-Dimensional Coordination Polymers Based on Ln(III) and 2,5-Diiodoterephthalates: Structures and Luminescent Behavior

Autor: Alexander S. Zaguzin, Mikhail A. Bondarenko, Pavel A. Abramov, Marianna I. Rakhmanova, Maxim N. Sokolov, Vladimir P. Fedin, Sergey A. Adonin
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Inorganics, Vol 10, Iss 12, p 262 (2022)
Druh dokumentu: article
ISSN: 10120262
2304-6740
DOI: 10.3390/inorganics10120262
Popis: Five new coordination polymers based on Ln3+ and 2,5-diiodoterephthalates (2,5-I-bdc)— {[La2(2,5-I-bdc)3(DMF)4]}·2DMF (1) and {[Ln2(2,5-I-bdc)3(DMF)4]} (Ln = La (2), Nd (3), Sm (4) and Eu (5))—were prepared and characterized by single crystal and powder X-ray diffractometry. Luminescent behavior was examined (the highest quantum yield is 4.5%); thermal stability was examined using thermogravimetric analysis.
Databáze: Directory of Open Access Journals
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