| Autor: |
Dalibor Tatar, Jelena Kojčinović, Berislav Marković, Aleksandar Széchenyi, Aleksandar Miletić, Sándor Balázs Nagy, Szilveszter Ziegenheim, Imre Szenti, Andras Sapi, Ákos Kukovecz, Kristijan Dinjar, Yushu Tang, David Stenzel, Gábor Varga, Igor Djerdj |
| Jazyk: |
angličtina |
| Rok vydání: |
2021 |
| Předmět: |
|
| Zdroj: |
Molecules, Vol 26, Iss 20, p 6115 (2021) |
| Druh dokumentu: |
article |
| ISSN: |
1420-3049 |
| DOI: |
10.3390/molecules26206115 |
| Popis: |
Efficient Lewis-acid-catalyzed direct conversion of aldehydes to 1,2-diketones in the liquid phase was enabled by using newly designed and developed ceria–zirconia-based high-entropy oxides (HEOs) as the actual catalysts. The synergistic effect of various cations incorporated in the same oxide structure (framework) was partially responsible for the efficiency of multicationic materials compared to the corresponding single-cation oxide forms. Furthermore, a clear, linear relationship between the Lewis acidity and the catalytic activity of the HEOs was observed. Due to the developed strategy, exclusively diketone-selective, recyclable, versatile heterogeneous catalytic transformation of aldehydes can be realized under mild reaction conditions. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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