| Autor: |
Jessica Flores Gonzalez, Olivier Cador, Lahcène Ouahab, Sergey Norkov, Viacheslav Kuropatov, Fabrice Pointillart |
| Jazyk: |
angličtina |
| Rok vydání: |
2018 |
| Předmět: |
|
| Zdroj: |
Inorganics, Vol 6, Iss 2, p 45 (2018) |
| Druh dokumentu: |
article |
| ISSN: |
2304-6740 |
| DOI: |
10.3390/inorganics6020045 |
| Popis: |
The reaction between the 2,2′-benzene-1,4-diylbis(6-hydroxy-4,7-di-tert-butyl-1,3-benzodithiol-2-ylium-5-olate biradical triad (L) and the metallo-precursor [Dy(hfac)3]·2H2O leads to the formation of a one-dimensional coordination polymer with the formula {[Dy(hfac)3(L)]·2C6H14}n (1). The X-ray structure reveals that the polymeric structure is formed by the bridging of the Dy(hfac)3 units with the multi-redox triad L. Single-crystal X-ray diffraction and UltraViolet-visible absorption spectroscopy confirm that the triad L in 1 is bound as a direduced, diprotonated form of o-quinone-extended tetrathiafulvalene-o-quinone (Q-exTTF-Q). Alternate Current (AC) measurements highlight a field-induced single-molecule magnet (SMM) behavior with an energy barrier of 20 K, and thus 1 can be described as a one-dimensional assembly of mononuclear SMMs bridged by the L triad. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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