Autor: |
Andy Kofi Agoe, Stavros G. Poulopoulos, Yerbol Sarbassov, Dhawal Shah |
Jazyk: |
angličtina |
Rok vydání: |
2024 |
Předmět: |
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Zdroj: |
Energies, Vol 17, Iss 18, p 4554 (2024) |
Druh dokumentu: |
article |
ISSN: |
1996-1073 |
DOI: |
10.3390/en17184554 |
Popis: |
Sewage sludge (SS) holds promise for environmental, agricultural, and energy applications. However, its direct use is limited due to contaminant concerns. Pyrolysis can turn SS into beneficial products like bio-oil and biochar. This study explores biochar production from SS pyrolysis and its potential for pollutant adsorption. The effects of pyrolysis temperature (500, 650, 850 °C) and SS particle size (800–1000 µm, 400–800 µm, 100–400 µm, ≤100 µm) on biochar yield and adsorption capacity for methylene blue and mercury were investigated. Regardless of particle size and temperature, SS-derived biochar exhibited second-order adsorption kinetics. Biochar with a particle size of 100–400 µm displayed the highest potential for methylene blue adsorption. Subsequent alkali treatment (biochar:NaOH = 3:4) of these particles significantly increased specific surface area from 27.5 m2/g to 144.27 m2/g and further enhanced adsorption capacities for both methylene blue (from 9 mg/g to 35 mg/g) and mercury (from 17 mg/g to 36 mg/g). These findings suggest that SS-derived biochar, particularly the 100–400 µm fraction with alkali treatment, presents a promising cost-effective adsorbent for water treatment, aligning with circular economy principles. |
Databáze: |
Directory of Open Access Journals |
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