Weak functional group interactions revealed through metal-free active template rotaxane synthesis

Autor: Chong Tian, Stephen D. P. Fielden, George F. S. Whitehead, Iñigo J. Vitorica-Yrezabal, David A. Leigh
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Nature Communications, Vol 11, Iss 1, Pp 1-10 (2020)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-020-14576-7
Popis: Weak interactions between functional groups are often difficult to characterize in host–guest complexes. Here, the authors report the metal-free active template synthesis of a series of rotaxanes that permit a range of kinetically stabilized, weak crown ether-axle interactions to be characterized in solution and the solid state.
Databáze: Directory of Open Access Journals