| Autor: |
Daniel Fuhrmann, Nick Hermann Bollfraß, Maik Icker, Harald Krautscheid |
| Jazyk: |
angličtina |
| Rok vydání: |
2023 |
| Předmět: |
|
| Zdroj: |
Crystals, Vol 13, Iss 5, p 721 (2023) |
| Druh dokumentu: |
article |
| ISSN: |
2073-4352 |
| DOI: |
10.3390/cryst13050721 |
| Popis: |
Three molecular sulfido complexes containing a Cd-S-Sn structure motive, [{(tmeda)Cd}3(SnPh)2S6] (1), [{(tmeda)Cd}2(SnPh2)2S4] (2) and [{(iPr3P)Cd}3Cd4(SnPh2)6S13] (3), have been synthesized and characterized by single-crystal X-ray diffraction. So far, 2 is the first cadmium tin sulfido complex soluble in common organic solvents. Analysis by 113Cd and 119Sn NMR spectroscopy shows a slow rearrangement in solution, while spin coupling between the nuclei can be used to identify the species in solution. Thermolysis of 2 results in CdS and SnS as solid thermolysis products. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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