Kinetics of Free Radical Polymerization of N-Substituted Amides and Their Structural Implications

Autor:	Anca Aldea, Ana-Maria Albu, Alina Nicolescu, Victorita Tecuceanu
Jazyk:	angličtina
Rok vydání:	2016
Předmět:	Materials of engineering and construction. Mechanics of materials TA401-492
Zdroj:	Advances in Materials Science and Engineering, Vol 2016 (2016)
Druh dokumentu:	article
ISSN:	1687-8434 1687-8442
DOI:	10.1155/2016/6430416
Popis:	Two N-substituted amides (N-acryloyl morpholine and N-methyl-N-vinylacetamide) were polymerized in different solvents using radical initiator. The tacticity of obtained polymers was determined by 400 MHz 1H-NMR and 13C-NMR. At a given temperature, the syndiotacticity increased with increasing the solvent polarity. This solvent effect may be related to the hydrogen bonding interaction among solvent, monomer, and/or growing species. A peculiar aspect regards the steric hindrance at the nitrogen atom.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/bf76ba55e9f841089ae34656c9d0d785 Zobrazit plný text záznamu View record in DOAJ Plný text ve formátu PDF