Measurement of L-Cysteine Amino Acid Using Modified Platinum Electrode by Nickel-Aluminum layered double hydroxide

Autor: Ali Ghaffarinead, Mehdi Ghaedrahmati, Razieh Salahandish
Jazyk: English<br />Persian
Rok vydání: 2019
Předmět:
Zdroj: شیمی کاربردی روز, Vol 14, Iss 51, Pp 103-120 (2019)
Druh dokumentu: article
ISSN: 2981-2437
DOI: 10.22075/chem.2019.12831.1257
Popis: L-Cysine (L-Cys) is one of the most important amino acids in the body and plays an important role in the immune system. In this study, the platinum electrode was modified by a Ni-Al double-layer hydroxide film (Pt /NiAlLDH) and used to measure L-Cys. Pt/NiAlLDH showed good catalytic activity for the oxidation of L-Cys. On this electrode, the oxidation of L-Cys occurs at a potential very lower than an unmodified platinum electrode, which occurred at about 500 mV. The catalytic oxidation peak currents depend on the L-Cys concentration with a logarithmic linear relation in the concentration range of 1×10-7 to 2.5×10-4 M and an experimental detection limit of 1×10-7 M. The proposed electrode was used for determination of L-Cys in a drug sample. This modified electrode is cheap and is quickly and easily prepared.
Databáze: Directory of Open Access Journals