Oxidovanadium(V) and Dioxidomolybdenum(VI) Complexes of N'-(3,5-Dichloro-2-hydroxybenzylidene)-4-fluorobenzohydrazide: Synthesis, Characterization, Crystal Structures and Catalytic Property

Autor:	Huan-Yu Liu, Yi-Shu Yin, Luo-Ju Yang, Xiao-Ling Zou, Ya-Fang Ye
Jazyk:	angličtina
Rok vydání:	2020
Předmět:	hydrazone vanadium complex molybdenum complex crystal structure catalytic property Chemistry QD1-999
Zdroj:	Acta Chimica Slovenica, Vol 67, Iss 1, Pp 130-136 (2020)
Druh dokumentu:	article
ISSN:	1318-0207 1580-3155
DOI:	10.17344/acsi.2019.5286
Popis:	N'-(3,5-Dichloro-2-hydroxybenzylidene)-4-fluorobenzohydrazide (H2L) was used to prepare oxidovanadium(V) complex [VOL(OEt)(MeOH)] (1) and dioxidomolybdenum(VI) complex [MoO2L(OH2)]·[MoO2L(EtOH)] (2). The complexes were characterized by IR, UV-Vis, NMR spectroscopy, and single crystal X-ray diffraction. X-ray analysis indicates that the complexes are mononuclear species with the metal atoms in octahedral coordination. The complexes were studied for catalytic oxidation property on some olefins with tert-butyl hydroperoxide as oxidant.
Databáze:	Directory of Open Access Journals
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