| Autor: |
Piotr Wałejko, Michał Dąbrowski, Lech Szczepaniak, Jacek W. Morzycki, Stanisław Witkowski |
| Jazyk: |
angličtina |
| Rok vydání: |
2015 |
| Předmět: |
|
| Zdroj: |
Beilstein Journal of Organic Chemistry, Vol 11, Iss 1, Pp 1893-1901 (2015) |
| Druh dokumentu: |
article |
| ISSN: |
1860-5397 |
| DOI: |
10.3762/bjoc.11.204 |
| Popis: |
The ROCM reactions of exo- and endo-2-cyano-7-oxanorbornenes with allyl alcohol or allyl acetate promoted by different ruthenium alkylidene catalysts were studied. The stereochemical outcome of the reactions was established. The issues concerning chemo- (ROCM vs ROMP), regio- (1-2- vs 1-3-product formation), and stereo- (E/Z isomerism) selectivity of reactions under various conditions are discussed. Surprisingly good yields of the ROCM products were obtained under neat conditions. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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