Crystal structure of aqua-trans-bis(dimethyl sulfoxide-κO)(pyridine-2,6-dicarboxylato-κ3O2,N,O6)nickel(II)
| Autor: | Chen Liu, Ashley C. Felts, Daisuke Takahashi, Wesley S. Kinden, Khalil A. Abboud |
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| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 73, Iss 5, Pp 777-779 (2017) |
| Druh dokumentu: | article |
| ISSN: | 2056-9890 20569890 |
| DOI: | 10.1107/S2056989017006090 |
| Popis: | In the title complex, [Ni(C7H3NO4)(C2H6OS)2(H2O)], the NiII cation is situated on a twofold rotation axis and exhibits a distorted octahedral NO5 coordination environment defined by a tridentate pyridine-2,6-dicarboxylic acid dianion (dpa2−), two dimethyl sulfoxide (DMSO) molecules, and a water molecule. In the crystal, the complex molecules are linked by O—H...O and C—H...O hydrogen bonds into a three-dimensional network whereby DMSO molecules from neighboring complexes overlap to form layers parallel to (001), alternating with layers of NiII–dpa2− moieties. The title complex is isotypic with its cobalt(II) analogue. |
| Databáze: | Directory of Open Access Journals |
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