DEARYLATION IN THE INTERACTIONS BETWEEN (Et3NH)HC2O4 OR (Et3NH)2C2O4 AND SnPh3Cl: INFRARED STUDY

Autor:	GORGUI AWA SECK, LIBASSE DIOP, ABOUBACARY SENE
Jazyk:	angličtina
Rok vydání:	2017
Předmět:	discrete structures hydrogen bonds IR technic lattice benzene molecules monochelating oxoanions octahedral environments Technology Engineering (General). Civil engineering (General) TA1-2040
Zdroj:	Journal of Engineering Studies and Research, Vol 23, Iss 2 (2017)
Druh dokumentu:	article
ISSN:	2068-7559 2344-4932
DOI:	10.29081/jesr.v23i2.84
Popis:	Five new oxalato, hydrogenoxalato and hydrogenocarbonato adducts (three) and complexes (two) obtained on allowing (Et3NH)HC2O4 or (Et3NH)2C2O4 to react with SnPh3Cl have been studied by infrared spectroscopy, then discrete structures suggested on the basis of spectroscopic data. The anions behave as monochelating ligands, the environments around the metallic centres being octahedral. In two of the compounds, the benzene molecules obtained in situ are lattice. In all these structures when considering the cation involved in extra hydrogen bonds, a supramolecular architecture may be obtained.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/be8c58b1b1a2416ebc011838ac101137 Zobrazit plný text záznamu View record in DOAJ