Catalytic bioethanol conversion into aromatic hydrocarbons with hydrogen peroxide

Autor:	V. F. Tretyakov, Thi Quỳnh Ny Tchan, R. M. Talyshinsky, A. M. Ilolov, N. A. Frantsuzova
Jazyk:	ruština
Rok vydání:	2013
Předmět:	bioethanol hydrogen peroxide aromatic hydrocarbons ethylene fuel топливо benzene ecology zeolite hzsm-5 initiation catalysis oligomerization hydroxylation peroxide radicals. Chemistry QD1-999
Zdroj:	Тонкие химические технологии, Vol 8, Iss 6, Pp 37-41 (2013)
Druh dokumentu:	article
ISSN:	2410-6593 2686-7575
Popis:	The initiating action of hydrogen peroxide on the catalytical transformation of ethanol into aromatic hydrocarbons was studied. It was shown that the total yield of aromatic hydrocarbons increases with increasing time of contact and temperature, when rapid coking of the surface of the zeolite-containing catalyst HZSM-5 occurs in the absence of hydrogen. The modifying action of hydrogen peroxide by the catalyst surface hydroxylation and initiation of the rate-limiting step of ethylene oligomerization with the participation of peroxide radicals HO2 • was hypothesized.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/be0072ea0c654e5ebe896de951a725ef Zobrazit plný text záznamu View record in DOAJ