NiFeRu Layered Double Hydroxide and Its Derivatives Supported on Graphite Foam as Binder-Free Cathode for Nonaqueous Li-O2 Batteries

Autor: Ming Song, Hua Tan, Lin Tian, Jing Li, Yan Xu, Liluo Shi, Limei Sun, Wenchang Zhuang, Xihua Du
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Frontiers in Energy Research, Vol 8 (2020)
Druh dokumentu: article
ISSN: 2296-598X
DOI: 10.3389/fenrg.2020.612093
Popis: Li-O2 batteries (LOBs) generally referred as Li-air batteries (LABs) potentially have a high specific capacity among all kinds of metal-ion batteries. However, it suffers severely from sluggish discharge/charge kinetics. A binder-free integrated cathode is fabricated which contains NiFeRu layered double hydroxide (NiFeRu LDH) nanosheets grown on a 3D conductive graphite foam (NiFeRu LDH@GF) in this work. This integrated 3D cathode exhibits a specific capacity of 3,085 mAh g−1 and a cycle life of 46. The electrochemical performances of NiFeRu LDH derived metal oxides (DMO@GF) by calcining NiFeRu LDH@GF at 350°C, 450°C, and 550°C are also been investigated. The 450°C obtained DMO@GF (450-DMO@GF) exhibits the highest catalytic activity for oxygen reduction/evolution reaction. The unique floccule-like and cross-connected structure of the 450-DMO@GF and its low charge transfer resistance are responsible for the outstanding electrochemical performance.
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