Activity measurement of Ga in liquid Ga-Pb alloys by EMF method with zirconia solid electrolyte

Autor: Katayama I., Živković Dragana, Manasijević Dragan, Oishi T., Živković Živan D., Iida T.
Jazyk: angličtina
Rok vydání: 2002
Předmět:
Zdroj: Journal of Mining and Metallurgy. Section B: Metallurgy, Vol 38, Iss 3-4, Pp 229-236 (2002)
Druh dokumentu: article
ISSN: 1450-5339
DOI: 10.2298/JMMB0204229K
Popis: EMF measurement of the electrochemical cell with zirconia as solid electrolyte was performed to determine the gallium activity from 950 to 1150K in the entire composition range of liquid Ga-Pb alloys. In the whole concentration range, activity of Ga shows moderately positive deviations from ideality, and activity of Pb which is derived by Gibbs- Duhem equation shows also positive deviation from ideality. These are compared with published data obtained by different experimental methods.
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