Determinação de constituintes químicos em madeira de eucalipto por Pi-CG/EM e calibração multivariada: comparação entre redes neurais artificiais e máquinas de vetor suporte

Autor: Cleiton Antônio Nunes, Claudio Ferreira Lima, Luiz Cláudio de Almeida Barbosa, Jorge Luiz Colodette, Paulo Henrique Fidêncio
Jazyk: English<br />Spanish; Castilian<br />Portuguese
Rok vydání: 2011
Předmět:
Zdroj: Química Nova, Vol 34, Iss 2, Pp 279-283 (2011)
Druh dokumentu: article
ISSN: 1678-7064
0100-4042
DOI: 10.1590/S0100-40422011000200020
Popis: Multivariate models were developed using Artificial Neural Network (ANN) and Least Square - Support Vector Machines (LS-SVM) for estimating lignin siringyl/guaiacyl ratio and the contents of cellulose, hemicelluloses and lignin in eucalyptus wood by pyrolysis associated to gaseous chromatography and mass spectrometry (Py-GC/MS). The results obtained by two calibration methods were in agreement with those of reference methods. However a comparison indicated that the LS-SVM model presented better predictive capacity for the cellulose and lignin contents, while the ANN model presented was more adequate for estimating the hemicelluloses content and lignin siringyl/guaiacyl ratio.
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