Rice husk-originating silicon–graphite composites for advanced lithium ion battery anodes

Autor: Hye Jin Kim, Jin Hyeok Choi, Jang Wook Choi
Jazyk: angličtina
Rok vydání: 2017
Předmět:
Zdroj: Nano Convergence, Vol 4, Iss 1, Pp 1-6 (2017)
Druh dokumentu: article
ISSN: 2196-5404
DOI: 10.1186/s40580-017-0118-x
Popis: Abstract Rice husk is produced in a massive amount worldwide as a byproduct of rice cultivation. Rice husk contains approximately 20 wt% of mesoporous SiO2. We produce mesoporous silicon (Si) by reducing the rice husk-originating SiO2 using a magnesio-milling process. Taking advantage of meso-porosity and large available quantity, we apply rice husk-originating Si to lithium ion battery anodes in a composite form with commercial graphite. By varying the mass ratio between these two components, trade-off relation between specific capacity and cycle life was observed. A controllable pre-lithiation scheme was adopted to increase the initial Coulombic efficiency and energy density. The series of electrochemical results suggest that rice husk-originating Si–graphite composites are promising candidates for high capacity lithium ion battery anodes, with the prominent advantages in battery performance and scalability.
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