Combined Sugarcane Pretreatment for the Generation of Ethanol and Value-Added Products

Autor: Sidnei Emilio Bordignon, Eduardo Ximenes, Olavo Micali Perrone, Christiane da Costa Carreira Nunes, Daehwan Kim, Maurício Boscolo, Eleni Gomes, Edivaldo Ximenes Ferreira Filho, Roberto da Silva, Michael R. Ladisch
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Frontiers in Energy Research, Vol 10 (2022)
Druh dokumentu: article
ISSN: 2296-598X
DOI: 10.3389/fenrg.2022.834966
Popis: In this work, we have tested individual and combination of applications of ozonolysis and liquid hot water (LHW) to pretreat sugarcane bagasse (SCB) for the removal of enzyme and/or microbial inhibitors and generation of potential value-added chemicals. A solid content with 80% cellulose and a liquid phase (liquor) rich in phenolic derived compounds (3 g.L−1) from lignin, sugars (>20 g.L−1), and other compounds, such as furfural and hydroxymethylfurfural (HMF), were generated. Maximal (59%) glucan conversion occurred in the presence of double-pretreated bagasse, which had 32–50% more glucan available than the samples that were individually LHW or ozone-pretreated, resulting in maximal ethanol production (92% after 42 h) from double-pretreated SCB enzyme hydrolyzate. In summary, this work showed that ozone reacts effectively with lignin without the use of any other chemical reagent, and LHW pretreatment, followed by a washing step, was effective in solubilizing and cleaning up the fiber enzyme and microbial inhibitory compounds with ozone being effective against phenolics. Moreover, the generated cellulose-rich substrate is readily fermentable. The acidic liquor fraction removed by sequential washings and containing mainly sugars and phenolic compounds may be evaluated for use in green chemistry bioconversions processes.
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