Bis(4-ferrocenylbenzoato-κO)tetrakis(methanol-κO)cadmium(II)
| Autor: | Seik Weng Ng, Jing-Wu Wang, Lian-Qing Song, Hong-Ying Zhao |
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| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 64, Iss 12, Pp m1624-m1624 (2008) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S160053680803907X |
| Popis: | The complete molecule of the title compound, [CdFe2(C5H5)2(C12H8O2)2(CH4O)4], is generated by crystallographic twofold symmetry, with the Cd atom lying on the rotation axis. The Cd atom is coordinated by the O atoms of the four methanol molecules and by the O atoms of the two carboxylate anions (the latter in cis geometry), resulting in a distorted CdO6 octahedron. The phenylene ring is almost coplanar with its adjacent cyclopentadienyl ring [dihedral angle = 8.2 (2)°]. The uncoordinated carboxylate O atom acts as acceptor to two O—H...O hydrogen bonds from the methanol molecules, giving rise to a layered network. |
| Databáze: | Directory of Open Access Journals |
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