Switching acidity on manganese oxide catalyst with acetylacetones for selectivity-tunable amines oxidation

Autor: Xiuquan Jia, Jiping Ma, Fei Xia, Mingxia Gao, Jin Gao, Jie Xu
Jazyk: angličtina
Rok vydání: 2019
Předmět:
Zdroj: Nature Communications, Vol 10, Iss 1, Pp 1-7 (2019)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-019-10315-9
Popis: Exploiting the organic adsorbate-metal oxide interaction to optimize the catalytic properties of metal oxides has been rarely explored. Here, the authors use enolic acetylacetones to modify the surface Lewis acid properties of manganese oxide, enabling a rational control of the oxidation selectivity of structurally diverse arylmethyl amines.
Databáze: Directory of Open Access Journals