| Autor: |
N.M.P. Truong, M. Michálková, M. Sedano, M.J. Pascual, R. Klement |
| Jazyk: |
angličtina |
| Rok vydání: |
2024 |
| Předmět: |
|
| Zdroj: |
Open Ceramics, Vol 20, Iss , Pp 100713- (2024) |
| Druh dokumentu: |
article |
| ISSN: |
2666-5395 |
| DOI: |
10.1016/j.oceram.2024.100713 |
| Popis: |
Glasses of compositions 40SiO2-25Al2O3-18Li2O-7LiF-(10-x-y)YF3-xErF3-yYbF3 (mol.%, x = 0.1, 0.5; y = 0, 0.4, 2, 4) were prepared by melt-quenching technique and milled into powders. Glass powder pellets were treated by hot pressing at defined temperatures to obtain the corresponding glass-ceramics (GCs). High-resolution TEM and XRD analysis revealed the crystallization of LiYF4 and LiAlSiO4 phases with nano-crystal size below 50 nm, resulting in translucent GCs. The density of GCs was 98–99.5 % compared to parent glasses. GCs exhibited intense up-conversion emission when excited by near-infrared light at 980 nm. As Er3+ concentration increased from 0.1 to 0.5 mol.% in the samples, notable enhancement in green and red emission intensities was indicated. Yb3+ ions significantly facilitated up-conversion emission through energy transfer to Er3+ ions, resulting in a higher luminescence yield compared to Er3+ single-doped GCs. The tuning of the red to green emission intensity ratio can be achieved by varying Er3+ and Yb3+ concentrations and Er3+/Yb3+ ratio. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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