Different Sequential Chemical Treatments Used to Obtain Bleached Cellulose from Orange Bagasse

Autor: Paulo Henrique Fernandes Pereira, Luana Lima Fernandes, Liziane Beatriz Ubirajara Santos, Heitor L. Ornaghi, Maria Odila Hilário Cioffi
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Journal of Natural Fibers, Vol 19, Iss 16, Pp 12849-12861 (2022)
Druh dokumentu: article
ISSN: 1544-0478
1544-046X
15440478
DOI: 10.1080/15440478.2022.2077506
Popis: The development of efficient pretreatments is widely used in biobased products aiming to add value to the residue. In this study, orange bagasse is investigated for cellulose extraction under moderate chemical sequential extraction conditions. Three pretreatments are evaluated: alkaline treatment, organosolv, and residue insoluble alcohol. Then, all pretreated samples are bleached. The results are analyzed by chemical composition, Fourier transformed infrared spectroscopy, X-ray diffraction, and thermogravimetric analysis. In general, similar results are observed for all bleaching samples, independently of the pretreatment. A similar cellulose amount is observed among the samples. When compared only to the pretreatments, alkaline shows to be a more effective way of presenting a higher crystallinity index. Hemicellulose and lignin are mostly removed after pretreatment. FTIR and XRD indicated that the pretreatment seems to be more effective in the first step. TG curves presented a more homogeneous pattern due to cellulose removal showing three steps for pre-treatment and two steps for bleached samples. The obtained cellulose has numerous potential applications, and a suitable route can be selected according to available reagents.
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