1-(5-Bromo-2-oxoindolin-3-ylidene)-4-phenylthiosemicarbazide
| Autor: | Adriano Bof de Oliveira, Inke Jess, Christian Näther, Leandro Bresolin, Katlen C. T. Bandeira |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2013 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 69, Iss 8, Pp o1337-o1338 (2013) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536813020497 |
| Popis: | In the title compound, C15H11BrN4OS, the least-squares plane through the 5-bromoisatin fragment forms a dihedral angle of 13.63 (14)° with the phenyl ring. The molecular conformation features intramolecular N—H...N and N—H...O hydrogen bonds. In the crystal, molecules are connected via pairs of N—H...O interactions into centrosymmetric dimers. Additionally, π–π stacking interactions link molecules into chains parallel to the a axis with short C...C distances being observed between the phenyl and thiocarbonyl [3.236 (8) Å] groups and between the thiocarbonyl and carbonyl [3.351 (4) Å] groups of stacked molecules. |
| Databáze: | Directory of Open Access Journals |
| Externí odkaz: |
|