Dichlorido[1-(2,6-dimethylphenylimino)-1,2-diphenylpropan-2-ol-κ2N,O]palladium(II) methanol monosolvate
| Autor: | Hua-Gang Yao, Dong-Sheng Shen, Ying-Tang Huang, Feng-Shou Liu |
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| Jazyk: | angličtina |
| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 67, Iss 10, Pp m1435-m1435 (2011) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536811037986 |
| Popis: | The title compound, [PdCl2(C23H23NO)]·CH3OH, was obtained by the reaction of 1-(2,6-dimethylphenylimino)-1,2-diphenylpropan-2-ol and palladium chloride in methanol. The Pd atom is four-coordinated by the O atom of a tertiary alcohol, the imine N atom of the hydroxylimine part of the bidentate ligand and by two chloride ions, forming a nearly square-planar geometry. The complex molecule and the uncoordinated methanol molecule are connected via an O—H...O hydrogen bond. |
| Databáze: | Directory of Open Access Journals |
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