Circulating-infiltrating preparation of hydrophilic nylon 6 membrane to hydrophobic MWCNT@nylon composite membrane

Autor: Mai Thanh Phong, Vinh-Dat Vuong, Nguyen Tan Tai, Muhammad Firdaus Mohd Nazeri, Tien-Thanh Nguyen, Pham Tan Thi, Thang Van Le
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Materials Research Express, Vol 10, Iss 11, p 115603 (2023)
Druh dokumentu: article
ISSN: 2053-1591
DOI: 10.1088/2053-1591/ad0523
Popis: The ion adsorption capacity has been added to the nylon 6 microfiltration (MF) membrane by grafting the fibers in its structure with carboxylated multi-walled carbon nanotubes (MWCNT-COOH). Through a direct three-step functionalization reaction with hexamethylenediamine (HMDA) and MWCNT-COOH, the multi-walled carbon nanotubes grafted nylon (MWCNT@nylon) fibers are made up of original nylon 6 and intermediate amino-enriched (nylon-NH _2 ) membranes. Chemical structure analysis shows that HMDA and MWCNTs were grafted to the nylon 6 fiber side wall, without causing damage to either the nylon 6 backbone or the pore size of the original membrane. The SEM images confirm this and further confirm that the plexus of MWCNT-COOH has a pore size of approximately 50 nm, covering the nylon 6 fibers. The sidewall of nylon-NH _2 and MWCNT@nylon fibers contains hydrophilic groups (amino and carboxylic), allowing the as-prepared membranes to reduce the wetting angle from about 70.3° to about 108.1°. This special structure opens new possibilities for polyamide membranes as well as mass production by the proposed simple method.
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