[1-(4-Hydroxy-2-oxidobenzylidene)-4-phenylthiosemicarbazonato-κ3N,O,S](1,10-phenanthroline-κ2N,N′)zinc(II)–4,4′-bipyridine (2/1)
Autor: | Seik Weng Ng, Mohd Jamil Maah, Kong Wai Tan, Chew Hee Ng |
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Jazyk: | angličtina |
Rok vydání: | 2009 |
Předmět: | |
Zdroj: | Acta Crystallographica Section E, Vol 65, Iss 8, Pp m920-m920 (2009) |
Druh dokumentu: | article |
ISSN: | 16005368 1600-5368 |
DOI: | 10.1107/S1600536809026245 |
Popis: | The ZnII atom in the title compound, [Zn(C14H11N3O2S)(C12H8N2)]·0.5C10H8N2, is N,N′-chelated by the N-heterocycle and N,O,S-chelated by the deprotonated Schiff base in a square-pyramidal environment. The hydroxy group of the Schiff base is a hydrogen-bond donor to 4,4′-bipyridine, which is located about a center of inversion, resulting in the formation of a supramolecular trimeric unit. |
Databáze: | Directory of Open Access Journals |
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