Molecular interaction studies of the volumetric behavior of binary liquid mixtures containing alcohols
| Autor: | Đorđević Bojan D., Radović Ivona R., Kijevčanin Mirjana Lj., Tasić Aleksandar Ž., Šerbanović Slobodan P. |
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| Jazyk: | angličtina |
| Rok vydání: | 2009 |
| Předmět: | |
| Zdroj: | Journal of the Serbian Chemical Society, Vol 74, Iss 5, Pp 477-491 (2009) |
| Druh dokumentu: | article |
| ISSN: | 0352-5139 1820-7421 |
| DOI: | 10.2298/JSC0905477D |
| Popis: | An attempt has been made to relate the volumetric effects involved in the binary mixtures of normal and branched alcohols and various components (aromatics, halo and nitroaromatics and haloaliphatics) with the molecular interactions of unlike molecules. This review is a condensation of research activities developed in recent years as results of a better understanding of volumetric behavior and a stronger insight into the complex structure of those mixtures. The influence of important contributions of a physical, chemical and geometrical nature that change excess molar volume, VE (positive, sigmoidal, negative) is considered and explained in detail. It appears that the balance between these contributions is quite sensitive to the behavior of the alcohol molecules in contact with the chosen compounds. |
| Databáze: | Directory of Open Access Journals |
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