Monoclinic polymorph of trans-tetraaquabis[(4-pyridylsulfanyl)acetato-κN]cobalt(II)
| Autor: | Dušan Mikloš, Jozef Miklovič, Jan Moncol, Peter Segľa, Marian Koman |
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| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 64, Iss 8, Pp m1089-m1089 (2008) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536808023593 |
| Popis: | The crystal structure of the title compound, [Co(C7H6NO2S)2(H2O)4], is a polymorph of the structure first reported by Du, Zhao & Wang [(2004). Dalton Trans, pp. 2065–2072]. The asymmetric unit of the title compound contains one half-molecule; the CoII atom lies on an inversion centre in a distorted octahedral geometry coordinated by two N atoms of the pyridine rings of the 4-pyridylthioacetate anions and four O atoms of water molecules. In the crystal structure, intermolecular O—H...O hydrogen bonds link the molecules, forming a three-dimensional network. |
| Databáze: | Directory of Open Access Journals |
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