Bis(9-aminoacridinium) bis(pyridine-2,6-dicarboxylato)cuprate(II) trihydrate
| Autor: | Hamid Reza Khavasi, Masoud Mirzaei, Shabnam Ahmadvand, Hossein Aghabozorg |
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| Jazyk: | angličtina |
| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 66, Iss 10, Pp m1318-m1319 (2010) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536810037499 |
| Popis: | The asymmetric unit of the title compound, (C13H11N2)2[Cu(C7H3NO4)2]·3H2O or (9-aminoAcr)[Cu(pydc)2]·3H2O, contains a Cu(pydc)2 (pydc = pyridine-2,6-dicarboxylate) anion, two protonated 9-aminoacridine (9-aminoAcr)+ counter-ions and three uncoordinated water molecules. The anion contains a six-coordinated Cu(II) atom within a distorted octahedral geometry. Non-covalent interactions i.e. N—H...O and O—H...O hydrogen bonds and intermolecular π–π contacts between the pyridine rings [centroid–centroid distance = 3.7773 (13) Å] and acridine rings [centroid–centroid distance = 3.4897 (13), 3.7784 (14) and 3.8627 (15) Å] result in the formation of a three-dimensional network. |
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