Bis(isonicotinamide-κN)silver(I) trifluoromethanesulfonate acetonitrile disolvate
| Autor: | Rafael A. Adrian, Sara J. Ibarra, Hadi D. Arman |
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| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: | |
| Zdroj: | IUCrData, Vol 6, Iss 10, p x211073 (2021) |
| Druh dokumentu: | article |
| ISSN: | 2414-3146 24143146 |
| DOI: | 10.1107/S2414314621010737 |
| Popis: | The central AgI atom of the title salt, [Ag(INAM)2](CF3SO3)·2CH3CN, where INAM is isonicotinamide (C6H6N2O), is twofold coordinated by the pyridine N atoms of two isonicotinamide ligands creating a slightly distorted linear molecular geometry. The formation of polymeric chains {[Ag(INAM)2]+}n, held together by discrete hydrogen bonds through the amide group of the INAM ligand leaves voids for non-coordinating acetonitrile molecules that interact the silver metal center via regium bonds. |
| Databáze: | Directory of Open Access Journals |
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