catena-Poly[calcium-bis[μ-N-(dimethylphosphinoyl)benzenesulfonamidato]]

Autor: Elizaveta A. Trush, Victor A. Trush, Tetyana Yu. Sliva, Irina S. Konovalova, Volodymyr M. Amirkhanov
Jazyk: angličtina
Rok vydání: 2009
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 65, Iss 10, Pp m1231-m1231 (2009)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536809032875
Popis: The crystal structure of the title calcium complex, [Ca(C8H11NO5PS)2]n, is composed of a polymeric chain, which is formed due to two bridging sulfonyl groups linking CaII ions in a O—S—O—Ca manner. Thus, the coordination environment of the CaII ions is composed of six O atoms belonging to the phosphoryl and sulfonyl groups of two chelate rings and two additional O atoms of two bridging sulfonyl groups. The coordination polyhedron of the central atom (2 symmetry) has a distorted octahedral geometry.
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