Autor: |
Zishuo Zhang, Jintong Zhang, Quan Gao, Yu Zhou, Mingyu Yang, Haiqun Cao, Tingting Sun, Gen Luo, Zhi-Chao Cao |
Jazyk: |
angličtina |
Rok vydání: |
2022 |
Předmět: |
|
Zdroj: |
Nature Communications, Vol 13, Iss 1, Pp 1-10 (2022) |
Druh dokumentu: |
article |
ISSN: |
2041-1723 |
DOI: |
10.1038/s41467-022-30693-x |
Popis: |
Transition-metal catalyzed alkylative cross-couplings are established, powerful tools for the installation of alkyl groups. Here, the authors unlock a C(sp3)–C(sp2) cross-coupling via the asymmetric activation of the aromatic C–O bond by bis-ligated nickel complexes for the synthesis of alkylated, axially chiral biaryl compounds. |
Databáze: |
Directory of Open Access Journals |
Externí odkaz: |
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