Crystal structures of (N-methyl-N-phenylamino)(N-methyl-N-phenylcarbamoyl)sulfide and the corresponding disulfane

Autor:	Matthew J. Henley, Alayne L. Schroll, Victor G. Young Jr, George Barany
Jazyk:	angličtina
Rok vydání:	2015
Předmět:	crystal structure organosulfur chemistry sulfide disulfane hydrogen bonding Crystallography QD901-999
Zdroj:	Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 11, Pp 1371-1374 (2015)
Druh dokumentu:	article
ISSN:	2056-9890 20569890
DOI:	10.1107/S2056989015018289
Popis:	The title compounds, (N-methyl-N-phenylamino)(N-methyl-N-phenylcarbamoyl)sulfide, C15H16N2OS, (I), and (N-methyl-N-phenylamino)(N-methyl-N-phenylcarbamoyl)disulfane, C15H16N2OS2, (II), are stable derivatives of (chlorocarbonyl)sulfenyl chloride and (chlorocarbonyl)disulfanyl chloride, respectively. The torsion angle about the S—S bond in (II) is −92.62 (6)°, which is close to the theoretical value of 90°. In the crystal of (II), non-classical intermolecular C—H...O hydrogen bonds form centrosymmetric cyclic dimers [graph set R22(10)], while inter-dimer C—H...S interactions generate chains extending along the b axis.
Databáze:	Directory of Open Access Journals
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