| Autor: |
Mohammad KarzarJeddi, Ossi Laitinen, Mehrdad Mahkam, Henrikki Liimatainen |
| Jazyk: |
angličtina |
| Rok vydání: |
2020 |
| Předmět: |
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| Zdroj: |
Materials & Design, Vol 196, Iss , Pp 109106- (2020) |
| Druh dokumentu: |
article |
| ISSN: |
0264-1275 |
| DOI: |
10.1016/j.matdes.2020.109106 |
| Popis: |
Different adsorbents have been applied to remove various anionic pollutants in water treatment processes. However, the development of economic, sustainable, and high-performance adsorbents is still a challenge. Herein, we introduce a new strategy to produce highly porous (98.96%), very low density (0.015 g/cm3), and cost-effective spherical and nanostructured hybrid aerogels, termed aerobeads, from cellulose nanofibers (CNF) and metal-organic frameworks (MOFs). The zwitterionic MOFs@CNF aerobeads (with 10–50 wt% MOF loading) were synthesized via simple dropping of a cross-linked hydrogel containing CNF and a binary mixture of anionic and cationic MOFs in liquid nitrogen, followed by freeze-drying. The flexible aerobeads (diameter of 2–3 mm) with hierarchical porous structure demonstrated an outstanding adsorption capacity toward both diclofenac (121.20 mg/g) and methyl orange (49.21 mg/g). Moreover, the aerobeads were easily collected after use from the solution without any complicated separation methods or the formation of secondary pollutants. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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Full Text from ScienceDirect