Bis{2-[2-(isopropylammonio)ethyliminomethyl]-6-methoxyphenolato}nickel(II) dithiocyanate
| Autor: | Jun-Tao Lei, Yan-Xia Jiang, Hong-Bo Ma |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 64, Iss 4, Pp m597-m598 (2008) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536808008052 |
| Popis: | The title complex, [Ni(C13H20N2O2)2](NCS)2, consists of a centrosymmetric mononuclear four-coordinate nickel(II) complex cation and two thiocyanate anions. The Ni atom is located on an inversion center and is coordinated by two phenol O atoms and two imine N atoms from two equivalent Schiff base ligands, in a square-planar geometry. In the crystal structure, the amino H atoms are involved in N—H...O hydrogen bonds with the phenol and methoxy O atoms of the ligand, and in N—H...N hydrogen bonds with the N atoms of the thiocyanate anions, which sit above and below the Ni atom. |
| Databáze: | Directory of Open Access Journals |
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