Practical Epoxidation of Olefins Using Air and Ubiquitous Iron-Based Fluorous Salen Complex

Autor:	Yamato Kato, Miho Kanoh, Hina Kobayashi, Takayuki Shioiri, Masato Matsugi
Jazyk:	angličtina
Rok vydání:	2024
Předmět:	air iron fluorous salen complex epoxidation olefin Organic chemistry QD241-441
Zdroj:	Molecules, Vol 29, Iss 5, p 966 (2024)
Druh dokumentu:	article
ISSN:	1420-3049
DOI:	10.3390/molecules29050966
Popis:	The epoxidation of olefins by substituting “air” for potentially harmful oxidants was achieved using an oxidation method that integrated a fluorous iron(III) salen catalyst derived from common metals and pivalaldehyde. Several aromatic disubstituted olefins were converted into their corresponding epoxides with high efficiency and quantitative yields. This reaction represents an environmentally friendly oxidation process that utilizes an abundant source of air and employs a readily available metal, iron, in the form of salen complexes, making it an environmentally conscious oxidation reaction.
Databáze:	Directory of Open Access Journals
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