Crystal structure of dilithium biphenyl-4,4′-disulfonate dihydrate
| Autor: | Hitoshi Kumagai, Satoshi Kawata, Nobuhiro Ogihara |
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| Jazyk: | angličtina |
| Rok vydání: | 2024 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 80, Iss 1, Pp 22-24 (2024) |
| Druh dokumentu: | article |
| ISSN: | 2056-9890 20569890 |
| DOI: | 10.1107/S2056989023010411 |
| Popis: | The asymmetric unit of the title compound, μ-biphenyl-4,4′-disulfonato-bis(aqualithium), [Li2(C12H8O6S2)(H2O)2] or Li2[Bph(SO3)2](H2O)2, consists of an Li ion, half of the diphenyl-4,4′-disulfonate [Bph(SO3−)2] ligand, and a water molecule. The Li ion exhibits a four-coordinate tetrahedral geometry with three oxygen atoms of the Bph(SO3−)2 ligands and a water molecule. The tetrahedral LiO4 units, which are interconnected by biphenyl moieties, form a layer structure parallel to (100). These layers are further connected by hydrogen-bonding interactions to yield a three-dimensional network. |
| Databáze: | Directory of Open Access Journals |
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