Multinuclear MR and MRI study of lithium-ion cells using a variable field magnet and a fixed frequency RF probe

Autor: Andrés Ramírez Aguilera, Florin Marica, Kevin J. Sanders, Md Al Raihan, C. Adam Dyker, Gillian R. Goward, Bruce J. Balcom
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Magnetic Resonance Letters, Vol 4, Iss 1, Pp 100090- (2024)
Druh dokumentu: article
ISSN: 2772-5162
DOI: 10.1016/j.mrl.2023.11.002
Popis: An exploratory multinuclear magnetic resonance (MR) and magnetic resonance imaging (MRI) study was performed on lithium-ion battery cells with 7Li, 19F, and 1H measurements. A variable field superconducting magnet with a fixed frequency parallel-plate radiofrequency (RF) probe was employed in the study. The magnetic field was changed to set the resonance frequency of each nucleus to the fixed RF probe frequency of 33.7 MHz. Two cartridge-like lithium-ion cells, with graphite anodes and LiNi0.5Mn0.3Co0.2O2 (NMC) cathodes, were interrogated. One cell was pristine, and one was charged to a cell voltage of 4.2 V. The results presented demonstrate the great potential of the variable field magnet approach in multinuclear measurement of lithium-ion batteries. These methods open the door for developing faster and simpler methods for detecting, quantifying, and interpreting MR and MRI data from lithium-ion and other batteries.
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