Pentacarbonyl-2κ5C-chlorido-1κCl-bis[1(η5)-cyclopentadienyl](μ-α-oxidobenzylidene-1:2κ2O:C)titanium(IV)tungsten(0)
| Autor: | Stephanie Cronje, Matthias W. Esterhuysen, I. B. Jacques Nel, Catharine Esterhuysen |
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| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 64, Iss 12, Pp m1534-m1534 (2008) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536808036465 |
| Popis: | The title compound, [TiW(C5H5)2(C7H5O)Cl(CO)5], consists of two metal centres, with a (tungstenpentacarbonyl)oxyphenylcarbene unit coordinated by a titanocene chloride. The oxycarbene group is nearly planar, with the phenyl ring twisted by an angle of 39.1 (2)° with respect to this plane. One of the cyclopentadienyl rings undergoes an offset face-to-face π–π interaction [3.544 (6) Å] with the symmetry-related cyclopentadienyl ring of a neighbouring molecule. |
| Databáze: | Directory of Open Access Journals |
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